Limits of validity
Many branches of classical mechanics are simplifications or approximations of more accurate forms; two of the most accurate being general relativity and relativistic statistical mechanics. Geometric optics is an approximation to the quantum theory of light, and does not have a superior "classical" form.
The Newtonian approximation to special relativity
In special relativity, the momentum of a particle is given by
where m is the particle's mass, v its velocity, and c is the speed of light.
If v is very small compared to c, v2/c2 is approximately zero, and so
Thus the Newtonian equation p = mv is an approximation of the relativistic equation for bodies moving with low speeds compared to the speed of light.
For example, the relativistic cyclotron frequency of a cyclotron, gyrotron, or high voltage magnetron is given by
where fc is the classical frequency of an electron (or other charged particle) with kinetic energy T and (rest) mass m0 circling in a magnetic field. The (rest) mass of an electron is 511 keV. So the frequency correction is 1% for a magnetic vacuum tube with a 5.11 kV direct current accelerating voltage.
The classical approximation to quantum mechanics
The ray approximation of classical mechanics breaks down when the de Broglie wavelength is not much smaller than other dimensions of the system. For non-relativistic particles, this wavelength is
where h is Planck's constant and p is the momentum.
Again, this happens with electrons before it happens with heavier particles. For example, the electrons used by Clinton Davisson and Lester Germer in 1927, accelerated by 54 volts, had a wave length of 0.167 nm, which was long enough to exhibit a single diffraction side lobe when reflecting from the face of a nickel crystal with atomic spacing of 0.215 nm. With a larger vacuum chamber, it would seem relatively easy to increase the angular resolution from around a radian to a milliradian and see quantum diffraction from the periodic patterns of integrated circuitcomputer memory.
More practical examples of the failure of classical mechanics on an engineering scale are conduction by quantum tunneling in tunnel diodes and very narrow transistor gates in integrated circuits.
Classical mechanics is the same extreme high frequency approximation as geometric optics. It is more often accurate because it describes particles and bodies with rest mass. These have more momentum and therefore shorter De Broglie wavelengths than massless particles, such as light, with the same kinetic energies.
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